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Second-generation biofuels : ウィキペディア英語版
Second-generation biofuels
Second generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of biomass. Biomass is a wide-ranging term meaning any source of organic carbon that is renewed rapidly as part of the carbon cycle. Biomass is derived from plant materials but can also include animal materials.
First generation biofuels are made from the sugars and vegetable oils found in arable crops, which can be easily extracted using conventional technology. In comparison, second generation biofuels are made from lignocellulosic biomass or woody crops, agricultural residues or waste, which makes it harder to extract the required fuel.
== Introduction ==
Second generation biofuel technologies have been developed because first generation biofuels manufacture has important limitations.〔Evans, G. ("International Biofuels Strategy Project. Liquid Transport Biofuels - Technology Status Report, NNFCC 08-017" ), National Non-Food Crops Centre, 2008-04-14. Retrieved on 2011-02-16.〕 First generation biofuel processes are useful but limited in most cases: there is a threshold above which they cannot produce enough biofuel without threatening food supplies and biodiversity. Many first generation biofuels depend on subsidies and are not cost competitive with existing fossil fuels such as oil, and some of them produce only limited greenhouse gas emissions savings. When taking emissions from production and transport into account, life-cycle assessment from first generation biofuels frequently approach those of traditional fossil fuels.〔(【引用サイトリンク】title=ADEME )
Second generation biofuels can help solve these problems and can supply a larger proportion of global fuel supply sustainably, affordably, and with greater environmental benefits.
First generation bioethanol is produced by fermenting plant-derived sugars to ethanol, using a similar process to that used in beer and wine-making (see Ethanol fermentation). This requires the use of 'food' crops, such as sugar cane, corn, wheat, and sugar beet. These crops are required for food, so, if too much biofuel is made from them, food prices could rise and shortages might be experienced in some countries. Corn, wheat, and sugar beet can also require high agricultural inputs in the form of fertilizers, which limit the greenhouse gas reductions that can be achieved. Biodiesel produced by transesterification from rapeseed oil, palm oil, or other plant oils is also considered a first generation biofuel.
The goal of second generation biofuel processes is to extend the amount of biofuel that can be produced sustainably by using biomass consisting of the residual non-food parts of current crops, such as stems, leaves and husks that are left behind once the food crop has been extracted, as well as other crops that are not used for food purposes (non-food crops), such as switchgrass, grass, jatropha, whole crop maize, miscanthus and cereals that bear little grain, and also industry waste such as woodchips, skins and pulp from fruit pressing, etc.
The problem that second generation biofuel processes are addressing is to extract useful feedstocks from this woody or fibrous biomass, where the useful sugars are locked in by lignin, hemicellulose and cellulose. All plants contain lignin, hemicellulose and cellulose. These are complex carbohydrates (molecules based on sugar). Lignocellulosic ethanol is made by freeing the sugar molecules from cellulose using enzymes, steam heating, or other pre-treatments. These sugars can then be fermented to produce ethanol in the same way as first generation bioethanol production. The by-product of this process is lignin. Lignin can be burned as a carbon neutral fuel to produce heat and power for the processing plant and possibly for surrounding homes and businesses. Thermochemical processes (liquefaction) in hydrothermal media can produce liquid oily products from a wide range of feedstock that has a potential to replace or augment fuels. However, these liquid products fall short of diesel or biodiesel standards. Upgrading liquefaction products through one or many physical or chemical processes may improve properties for use as fuel.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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